Type about:customizing<enter> in the address bar. In the new window, look for the icon. When you find it, hold down the left button on it, and move it to where you want it to be. You can move any of the icons you want from here, but some icons are locked in place.

There is also a Restore Defaults button at the bottom middle.

https://support.mozilla.org/en-US/kb/customize-firefox-controls-buttons-and-toolbars

Open Customize and use the Restore Defaults. Lower portion, off-center right.

You may have removed the button(s) from the Navigation Toolbar by accident.

If you right-click a toolbar item in normal (non-customize) mode then you can remove this item from the toolbar.

• "Remove from Toolbar" will remove this item from the Navigation Toolbar and moves it to the Customize palette ("3-bar" Firefox menu button > Customize)
• "Move to Menu" will move this item to the "3-bar" Firefox menu button drop-down list
• "Move to Toolbar" in the "3-bar" Firefox menu button drop-down list will move this item to the toolbar