This could be a problem with the favicons.sqlite that stores favicon data.

You can check for problems with the places.sqlite and favicons.sqlite files in the Firefox profile folder.

• use "Verify Integrity" button on the "Help -> Troubleshooting Information" (about:support) page

In case errors are reported with "Verify Integrity" close and restart Firefox and retry.

If "Verify Integrity" cannot repair places.sqlite, rename/remove all places.sqlite and favicons.sqlite files in the Firefox profile folder. Firefox will rebuild places.sqlite and restore the bookmarks from a recent JSON backup in the bookmarkbackups folder.

• keep a backup copy of places.sqlite in case a new places.sqlite database has to be created

See also:

• https://support.mozilla.org/en-US/kb/Bookmarks+not+saved#w_fix-the-bookmarks-file
• https://support.mozilla.org/en-US/kb/fix-bookmarks-and-history-will-not-be-functional

You can use the button on the "Help -> Troubleshooting Information" (about:support) page to go to the current Firefox profile folder or use the about:profiles page.

• Help -> Troubleshooting Information -> Profile Directory:
  Windows: Show Folder; Linux: Open Directory; Mac: Show in Finder
• http://kb.mozillazine.org/Profile_folder_-_Firefox

I had a hard time stumbling upon the place where I could find these folders and files, but I did more or less by dumb luck (a 'show in Finder' [Mac OS] command did the trick) but it fixed the problem! So many thanks for this. And it was a relief to see that it was a minor corruption in my copy of Firefox, and not some intrusive behavior by FB.